分析化學(xué)（雙語(yǔ)版）

Chapter 1 Introduction 緒論
1.1 The nature of analytical chemistry 分析化學(xué)的性質(zhì)
1.2 The role of analytical chemistry 分析化學(xué)的作用
1.3 The classification of analytical chemistry分析化學(xué)的分類
1.4 The total analytical process分析全過程
Terms to understand
重點(diǎn)內(nèi)容概述
Chapter 2 Errors and Data Treatment in Quantitative Analysis 定量分析中的誤差及數(shù)據(jù)處理
2.1 Fundamental terms of errors誤差的基本術(shù)語(yǔ)
2.2 Types of errors in experimental data實(shí)驗(yàn)數(shù)據(jù)中的誤差類型
2.2.1 Systematic errors 系統(tǒng)誤差
2.2.2 Random errors偶然誤差
2.3 Evaluation of analytical data分析數(shù)據(jù)的評(píng)價(jià)
2.3.1 Tests of significance顯著性檢驗(yàn)
2.3.2 Rejecting data可疑值取舍
2.4 Significant figures有效數(shù)字
Problems
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Chapter 3 Titrimetric Analysis滴定分析法
3.1 General principles基本原理
3.1.1 Relevant terms of titrimetric analysis滴定分析相關(guān)術(shù)語(yǔ)
3.1.2 The preparation of standard solution and the expression of concentration 標(biāo)準(zhǔn)溶液的配制與濃度表示方法
3.1.3 The types of titrimetric reactions滴定反應(yīng)類型
3.2 Acid-base titration酸堿滴定
3.2.1 Acid-base equilibria 酸堿平衡
3.2.2 Titration curves滴定曲線
3.2.3 Acid-base indicators酸堿指示劑
3.2.4 Applications of acid-base titration酸堿滴定的應(yīng)用
3.3 Complexometric titration配位滴定
3.3.1 Metal-chelate complexes金屬螯合物
3.3.2 EDTA 乙二胺四乙酸
3.3.3 EDTA titration curves EDTA滴定曲線
3.3.4 Metal Ion indicators金屬離子指示劑
3.3.5 Applications of EDTA titration techniques EDTA滴定方法的應(yīng)用
3.4 Oxidation-reduction titration氧化還原滴定
3.4.1 Redox reactions氧化還原反應(yīng)
3.4.2 Rate of redox reactions氧化還原反應(yīng)的速率
3.4.3 Titration curves滴定曲線
3.4.4 Redox indicators氧化還原指示劑
3.4.5 Applications of redox titrations氧化還原滴定的應(yīng)用
3.5 Precipitation titration沉淀滴定
3.5.1 Precipitation reactions沉淀滴定反應(yīng)
3.5.2 Titration curves滴定曲線
3.5.3 End-point detection終點(diǎn)檢測(cè)
Problems
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Chapter 4 Potentiometry 電位分析法
4.1 Introduction簡(jiǎn) 介
4.1.1 Classes and characteristics分類及性質(zhì)
4.1.2 Definition定 義
4.2 Types of potentiometric electrodes電極種類
4.2.1 Reference electrodes 參比電極
4.2.2 Indicator electrodes指示電極
4.2.3 Electrode response and selectivity電極響應(yīng)及選擇性
4.3 Potentiometric methods and application電位法及應(yīng)用
4.3.1 Direct potentiometric measurement 直接電位法
4.3.2 Potentiometric titrations電位滴定
4.3.3 Applications of potentiometry 電位法應(yīng)用
Problems
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Chapter 5 Chromatography色譜法
5.1 An introduction to chromatographic methods色譜法概述
5.2 Fundamental theory of gas chromatography氣相色譜基本原理
5.2.1 Plate theory塔板理論
5.2.2 Kinetic theory(rate theory) 速率理論
5.2.3 The resolution Rs as a measure of peak separation 分離度
5.3 Gas chromatography 氣相色譜
5.3.1 Components of a gas chromatograph 氣相色譜儀的組成
5.3.2 Stationary phases for gas-liquid chromatography 氣液色譜固定相
5.3.3 Applications of gas-liquid chromatography 氣液色譜的應(yīng)用
5.3.4 Adsorption chromatography 吸附色譜
5.4 High performance liquid chromatography 高效液相色譜
5.4.1 Instrumentation 儀器組成
5.4.2 High-performance partition chromatography 高效分配色譜
5.5 Miscellaneous separation methods 其他分離方法
5.5.1 High-performance ion-exchange chromatography 高效離子交換色譜
5.5.2 Capillary electrophoresis 毛細(xì)管電泳
5.5.3 Planar chromatography 平板色譜
Problems
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Chapter 6 Atomic Absorption Spectrometry原子吸收光譜分析法
6.1 Introduction 概述
6.2 Principles 原理
6.2.1 The process of AAS，resonance line and absorption line 原子吸收光譜法的過程，共振線及吸收線
6.2.2 The number of ground atom and the temperature of flame 基態(tài)原子數(shù)與光焰溫度
6.2.3 Quantitative analysis of AAS原子吸收光譜定量分析
6.3 Instrumentation 儀 器
6.3.1 Primary radiation sources 光源
6.3.2 Atomizer 原子儀器
6.3.3 Optical dispersive systems 分光系統(tǒng)
6.3.4 Detectors 檢測(cè)器
6.3.5 Signal measurements 信號(hào)測(cè)量
6.4 Quantitative measurements and interferences 定量測(cè)定及干擾
6.4.1 Quantitative measurements 定量測(cè)定
6.4.2 Interferences 干擾
6.4.3 Sensitivity
6.5 Applications of AAS原子吸收光譜法的應(yīng)用
Problems
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Chapter 7 Ultraviolet and Visible Spectrophotometry 紫外-可見分光光度法
7.1 Introduction簡(jiǎn) 介
7.2 Ultraviolet and visible absorption spectroscopy 紫外-可見吸收光譜
7.2.1 Introduction for radiant energy 輻射能簡(jiǎn)介
7.2.2 Selective absorption of radiation and absorbance spectrum 物質(zhì)對(duì)光的選擇性吸收和吸收光譜
7.2.3 Absorbing species and electron transition 吸收物質(zhì)與電子躍遷
7.3 Law of absorption吸收定律
7.3.1 Lambert-Beer's law朗伯-比爾定律
7.3.2 Absorptivity吸光系數(shù)
7.3.3 Apparent deviations from Beer's law對(duì)比爾定律的明顯偏離
7.4 Instruments儀器
7.5 General types of spectrophotometer分光光度計(jì)種類
7.6 Application of UV-Vis absorption spectroscopy 紫外-可見吸收光譜的應(yīng)用
7.6.1 Application of absorption measurement to qualitative analysis 光吸收測(cè)定在定性分析上的應(yīng)用
7.6.2 Quantitative analysis by absorption measurements 光吸收測(cè)量定量分析法
7.6.3 Derivative spectrophotometry 導(dǎo)數(shù)分光光度法
Problems
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Chapter 8 Infrared Absorption Spectroscopy紅外吸收光譜
8.1 Theory of infrared absorption紅外吸收基本原理
8.1.1 Dipole changes during vibrations and rotations 振轉(zhuǎn)運(yùn)動(dòng)中的偶極距變化
8.1.2 Mechanical model of stretching vibrations 伸縮振動(dòng)機(jī)械模型
8.1.3 Quantum treatment of vibrations 振動(dòng)的量子力學(xué)處理、
8.1.4 Types of molecular vibrations分子振動(dòng)形式
8.2 Infrared instrument components紅外儀器組成
8.2.1 Wavelength selection波長(zhǎng)選擇
8.2.2 Sampling techniques 采樣技術(shù)
8.2.3 Infrared spectrophotometers for qualitative analysis 定性分析用紅外分光光度計(jì)
8.2.4 Other techniques其他技術(shù)
8.3 The group frequencies of functional groups in organic compounds 有機(jī)化合物官能團(tuán)的特征頻率
8.4 The factors affecting group frequencies 影響基團(tuán)特征吸收頻率的因素
8.4.1 Adjacent groups 鄰近基團(tuán)的影響
8.4.2 Hydrogen bonding 氫鍵
8.5 Qualitative applications to structural analysis 結(jié)構(gòu)分析的定性應(yīng)用
Problems
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Chapter 9 Nuclear Magnetic Resonance Spectroscopy 核磁共振波譜法
9.1 Theory of nuclear magnetic resonance 核磁共振理論
9.1.1 Quantum description of NMR NMR 的量子描述
9.1.2 Classical description of NMR NMR 的經(jīng)典描述
9.2 Experimental methods of NMR spectroscopy NMR波譜的實(shí)驗(yàn)方法
9.3 The chemical shift of protons in organic compounds 有機(jī)化合物中質(zhì)子的化學(xué)位移
9.3.1 Souroe of the chemical shift化學(xué)位移產(chǎn)生原
9.3.3 Environmental effects on the chemical shift of proton NMR spectra 影響NMR波譜中質(zhì)子化學(xué)位移的環(huán)境因素
9.4 Spin-Spin coupling 自旋-自旋耦合
9.4.1 Source of Spin-Spin coupling and splitting 自旋-自旋耦合與裂分的產(chǎn)生原因
9.4.2 Coupling constant耦合常數(shù)
9.4.3 Rule8 governing the interpretation of spectra光譜解析規(guī)則
9.5 Qualitative applications of proton NMR質(zhì)子NMR波譜的定性應(yīng)用
Problems
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Chapter 10 Mass Spectrometry質(zhì)譜法
10.1 The principle of mass spectroscopy and mass spectrometer 質(zhì)譜法和質(zhì)譜儀的原理
10.2 Mass spectra質(zhì)譜圖
10.2.1 The electron impact ionization process 電子轟擊離子過程
10.2.2 The molecular ion 分子離子
10.2.3 Isotope peaks 同位素離子峰
10.2.4 Peaks for collision products 碎片離子峰
10.2.5 The base peak 基峰
10.3 Qualitative applications of mass spectroscopy 質(zhì)譜法的定性應(yīng)用
Problems
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重點(diǎn)內(nèi)容概述
Appendix 附錄
References 參考文獻(xiàn)